Found inside – Page 204These compounds have affinity for textile fibers and are capable of conversion to copper phthalocyanine in the fiber . ... The crystallization problem is doubly complicated by the fact that the solubility of copper phthalocyanine in ... 10g. Phthalocyanine Blue 1501C is a solvent-unstable Cu-Phthalo blue pigment with a reddish blue shade. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Aqueous solubility of copper phthalocyanine-3,4',4″,4″'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter. +F3����̚�Y���UŐ7:���/�S��x0Q��%��8�0�s(���Ɲ��L�%=! Experimental Materials Copper phthalocyanines (CuPc) standard was purchased from Sigma-Aldrich (St. Louis, MO, USA). Privacy Policy k9�o�z(+̅h��a&���K{誔.��\[}��r�! ,ANU�S���� 9��������R����s�7h�5Ev'���� ��E3�J;��P�k���ag��F�`G���4S����[d�:�ILD�^e�{�dљM9�[��+�ȸb�NIX�֜�F�D��O9�ֳP�>�IV� ʝ�lj"J�i?���[[�Q�[8���[�T�^�=?��U�D��1IL��0M-��?$E#��Z+�=�p��L$�ߐ��fm�< This work presents the synthesis and characterization of non-aggregated and highly soluble copper(II) and tin(II) phthalocyanines substituted with 2,6-dimethoxyphenoxy groups at the non-peripheral (alpha) and peripheral (beta) positions. Shop a large selection of products and learn more about Alfa Aesar Copper(II) phthalocyanine. Phthalocyanine and derived metal complexes (MPc) tend to aggregate and, thus, have low solubility in common solvents. endobj It has a role as a fluorochrome. 3 0 obj Phthalocyanine Dyes (or phthalocyanine pigments), a group of dyes, derivatives of tetrabenzotetraazoporphyrin (phthalocyanine) and its complex compounds with metals. More. Excellence in pigment manufacturing and supply. The two most common structures in CuPc are the β phase and the metastable α phase. Description of first aid measures Found inside – Page 77For example, in Cu-phthalocyanine the Q-band is observed as a single peak at ... The need for light-absorbing compounds with higher solubility in organic ... Found inside – Page 361However , pigment derivatives of HPOP that are soluble in organic solvents can be ... These include sulfonated derivatives of copper phthalocyanines ... The α phase has a larger overlap and thus, a smaller Cu-Cu spacing (~3.8 à ) compared to the β phase (~4.8 à ). Abstract: A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R 1 is --(C a H 2a O) m (C b H 2b O) n H, R 2 is H or . Molecular Weight. Concentrated sulphuric acid and ortho-phosphoric acid were from Qrëc (New Zealand). They show excellent solubility and non-aggregated species in common organic . MonoIsotopic Mass: 575.079394. General information To generate high quality HTM film, 4-tertbutylpyridine (tBP) was doped into CuPc-OBu to prepare the film and then removed by annealing. compared with pristine CuPc molecules with low solubility, limitation of thermal evaporation approach that is . CAS No.147-14-8 Pigment Blue 15 : 3 Copper phthalocyanine blue For Printing Inks. 1. The following article is from The Great Soviet Encyclopedia (1979). Aqueous solubility of copper phthalocyanine-3,4′,4″,4″′-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Found inside – Page 12Brighter shades of green with better solubility are made by chlorosulfonation of copper phthalocyanine, followed by zinc or iron reduction of the sulfonyl ... endobj The authors have performed a proper study of different metal-phthalocyanines in a variety of solvents and their solubility, among other things. z0��X�)A,� B�ꨟ~TM�����ª)~��}m˪�L����(���. Water Solubility: 0.1 g/100 mL at 20℃ . Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex Ryota Terao , Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan Get medical attention. Copper phthalocyanine is a chemical complex compound between copper and phthalocyanine.It is a blue solid that is in the form of a powder or needles with a metallic sheen. Water-soluble copper phthalocyanine dyes free from cellulose reactive groups . nines to grant solubility,1 in aqueous ambience in particular, e.g. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing. Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper. Fax: 1-978-521-6366 4 0 obj Found inside – Page 325Jiang et al. demonstrated that water‐soluble single‐walled CNHs and metal ... SWNHs‐tetrasulfonic acid tetrasodium salt copper phthalocyanine (TSCuPc) show ... We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2 . The first known appearance of an unknown blue by-product (which we now know was metal-free phthalocyanine) was reported in 1907. Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. [Various characteristics of the toxic effect of water-soluble phthalocyanine dyes]. Found inside – Page 92The solubility of metal phthalocyanines in concentrated sulfuric acid has been ... have shown that both metal-free and copper phthalocyanines undergo atomic ... <> Copper phthalocyanine is the main blue pigment.It is used in many different ways for paints, plastics and printing inks.Copper phthalocyanine pigments have a high temperature resistance and excellent fastness properties to . 2 0 obj endobj Dry Organic Pigment Copper phthalocyanine - Green - 5400A C.I. copper(II) acetate). Organic photovoltaic (OPV) planar heterojunction devices based on an aqueous solution processed 3,4′,4′′,4′′′-copper(II) phthalocyanine-tetrasulfonic acid tetrasodium salt (TSCuPc) donor layer and a fullerene (C60) acceptor have been fabricated demonstrating power conversion efficiencies of up to 0.32% and an open circuit voltage (VOC) of almost 0.6 V. United States Patent 4634555 . Skin Contact Wash off immediately with plenty of water for at least 15 minutes. [Article in Russian] Imaging Science and Photochemistry ›› 2011, Vol. Water-soluble bases for transferring the sulfonic acid out of the organic phase back into the aqueous phase and, at the same time, into the desired water-soluble copper phthalocyanine salt are suitably, for example, alkali metal bases, ammonium hydroxide or hydrophilic amines. This produces toxic fumes. The applications of CuTCPc as donor and interlayer materials in solar cell devices are investigated. 5 OUTLOOK. | From what understand, metal phthalocyanines are typically prepared by synthesis of phthalocyanine in the presence of metal salts (copper salts in my case, which aren't particularly hard to make, e.g. We have subsequently exposed these films to the vapours of methanol, ethanol and propanol. The results of which can be easily document examination. ������������!�[����� Found inside – Page 132... dyestuffs of a range possess similar re— activity, solubility, and affinity. ... copper phthalocyanines) and the reactive group reduce the affinity and ... �X��EM��#���Q�m��e8X 10, 52, 53 Notably, the synthesized conjugated PcCu-MOFs are potential electrode materials for dual-ion batteries because . Found inside – Page 266The solubility problem has also been addressed in another art, that of dyes and pigments ... 503,029, which teaches a way to prepare copper phthalocyanines, ... Clear, Tungstosilicic acid hydrate, Reagent Grade. The most widely used phthalocyanine dye is copper phthalocyanine (I), a . [24], InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2, c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8[Cu-2]158)=nc2=n13)c=cc=c9)=[n+]56)[n+]48, Except where otherwise noted, data are given for materials in their. PMID: 17608196. and Hassan, E.K. China Business Portal ChinaChemNet KoreaChemNet. By browsing our website without changing the browser settings you grant us permission to store that information on your device. Analysis by GPC shows that narrow . More than 94m2 surface area 30 ~ / g. Oil Absorption 34 ~ 85g/100g. Functional perovskite solar cells can be made by using a simple, inexpensive and stable soluble tetra-n-butyl-substituted copper phthalocyanine (CuBuPc) as a hole transporter. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Found inside... Acid-soluble Extenders, Organic Colors and Lakes, Copper Phthalocyanine Blue, Identification, Basic Dye Derivatives, Other Organic Coloring Matter, ... Found inside – Page 1244In particular, this method is suitable for copper(II) phthalocyanine, which displays no significant solubility in any organic solvent and is stable in ... Grinding the pigments in the presence of soluble salts, which can be washed out in the purification . Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. %PDF-1.5 Catal. hebei crovell biotech co. ltd 1YR. Mixture Not applicable SECTION 4: First aid measures 4.1. Pigment Blue 15:1 - 8801DI. Publication Types: Store in a cool, dry, well-ventilated area away from incompatible substances. Copper(II) phthalocyanine Copper phthalocyanin Copper .beta.-phthalocyanine Copper(2+) phthalocyanine Synonyms.alpha.-Copper phthalocyanine .eta.-Copper phthalocyanine Copper phthalocyanine blue Copper tetrabenzoporphyrazine Cromofine blue 4950 Cromophtal blue 4G Cupric phthalocyanine Cyan blue BNC 55-3745 Cyanine blue BB and others Cyan . Decomposes on heating. Found inside – Page 8physical properties such as solubility , and photochemical , dielectric , and ... Commercial manufacturing methods of phthalocyanine and copper ... We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess CuPcTs as a humidity-sensing material. In recent years, interest has been focused on the synthesis of new types of soluble and . CID 433865 (21,23-Didehydrophthalocyanine) Component Compounds. CAS No: 147-14-8Molecular Weight: 578.08492Molecular Formula: C 32 H 18 CUN 8 - 4Names and Identifiers Properties Safety and Handling NMR Spectrum Synthesis Route Precursor and Product Computational chemical data 458 Suppliers. Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex Ryota Terao , Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan Found inside – Page iAimed at a better and clearer understanding of the latest developments in the hybrid perovskite field, this is a must-have for material scientists, chemists, physicists and engineers entering or already working in this booming field. 480 ° C melting point. Found inside – Page 11474160, is an alpha crystal that offers a red shade and the poorest stability of the copper phthalocyanines and as such is referred to as a crystallizing ... Found inside – Page 89For example , copper tetrakis - 4- ( ethylsulfamoyl ) phthalocyanine ( VIb ) does not dissolve in chloroform , but is somewhat soluble in acetone , whereas its diethyl - substituted analog ( III ) is readily soluble in chloroform ... All Rights Reserved. Dry Organic Pigment Copper phthalocyanine Blue - C.I. !08� ��,��n=B���C+Y����+K����|�އ պa����t]�S1�]yYVw�&�\���tC`1c��L{(M�MaL1�+�{�h�p@N w�.ҕ��QNq�*C��Ah� N��7����峬�����U�!�)���5�ɒ= Pr�3�/1~*�q��J�s̡�@����k����D�p9����)]�HЯWJMc� 8��UE+���ˋ�)��_�K,�ϱ���q��U����Gv�>�Uv�����_�wK�s�BKz�����n����t��WyȖ��L�'��b��@�|$��_�?�?aa) Nitinol Nickel Titanium Shape Memory Alloys, Specpure® Inorganic Standards for Water Analysis, Specpure® Oil-Based Standards for Wear Metal Analysis, Specpure® XRF Standards for Petroleum Products, Cellular Growth & Attachment Factors - BT Products, POCO Electron Beam Crucibles & Hearth Shields (Carbon Graphite), Boron, Phosphorus, Silicon, and Sulfur Compounds, Sugars, Steroids, Amino Acids, and Nucleotides, Precious Metal Compounds - Homogeneous Catalysts. COPPER(II) PHTHALOCYANINE Safety Data Sheet 06/14/2016 EN (English US) SDS ID: AKC261 2/6 Name Product identifier % GHS-US classification Copper(II) phthalocyanine (CAS No) 147-14-8 95 - 100 Not classified 3.2. The dye will not dissolve but Tween-80 helps incorporate and disperse it in an aqueous solution. The phthalocyanine dyes we work with generally contain a copper atom at the center of the phthalocyanine ring, so I always assumed the copper was necessary to the color. Recent data present the synthesis of metallated phthalocyanines without any Physical Properties: Specific Gravity (200 C) Copper (II) phthalocyanine, beta-form, Dye content 90 %. %���� Catalog Sales & Customer Service In general, a crude copper phthalocyanine is produced by reacting phthalic anhydride, urea, copper/copper salt and ammonium molybdate (catalyst) in high-boiling solvent such as o-nitrotoluene, trichlorobenzene or alkyl benzenes. The phthalocyanines have been characterized by common spectroscopic techniques. Found inside – Page 118HZPc, CuPc, and halogenated phthalocyanines have very poor solubility in organic solvents and water. A maximum of a few milligrams per liter may be achieved ... The synthesis, crystal structure, and electronic properties of perfluoro-isopropyl-substituted perfluorophthalocyanine bearing a copper atom in the central cavity (F 64 PcCu) are reported. Found inside – Page 413186 Copper - nickel - aluminum alloys microetching 104 ( T ) Copper - nickel binary ... acid applications , agricultural ..387 ( T ) Copper phthalocyanine . It is majorly used in a variety of energy conservation based applications. The basic copper phthalocyanine has a very low solubility in water (0.009 m g/L) and in octanol (0.000 4 m g/L). Found inside – Page 1300Temperature dependence of the solubility of copper phthalocyanines in sulphuric acid . CuPc Cupcalis initial Hysa , concn . , M acidity function , Ho solubility 10'S , M exponent of the equili . brium const . for the dissolution process ... Mixture Not applicable SECTION 4: First aid measures 4.1. Phthalocyanine is an intensely blue-green-colored aromatic macrocyclic compound that is widely used in dyeing and the first phthalocyanine (Pc) was synthesized accidentally in 1907 as an unidentified blue compound when o-cyanobenzamide was heated at high temperature and that substance is currently known to be the metal-free phthalocyanine [1]. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. H-Bond Acceptor: 8. Found inside – Page 428Luxol fast blue is the amine salt of a sulfonated copper phthalocyanine . ... from investigations on the solubility of copper phthalocyanin ( CuPC ) -lipid ... Found inside – Page 554Thus, a water-soluble composite of oxidized MWCNTs and sulfonic acid sodium salt derivatized copper phthalocyanine for application in bilayer organic solar ... Found inside – Page 296Originally, the water-soluble sulfonated copper phthalocyanines CI Direct Blues 87 and ... macrocyclic ring of the phthalocyanine system to attack by ozone. 74260. email: ecommerce@alfa.com, Specialty/Bulk Sales Excellence in pigment manufacturing and supply. Email: breeduan@crovellbio.com. Ziyu Lv, College of Electronic Science and Technology, Shenzhen University, Shenzhen, 518060 P. R. China . Found inside – Page 29254However , based on their of copper monochlorophthalocyanine hardness of 50 mg / L , the acute criterion extremely low solubility in water , their were 2,354 ... Copper(II) phthalocyanine-tetrasulfonic Acid Tetrasodium Salt is generally immediately available in most volumes. 147-14-8. Chemical Formula. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP . The present application relates to water-soluble copper phthalocyanine dyestuffs of the formula I ##STR1## in which CuPc is a copper phthalocyanine radical; X is a straight-chain or branched alkylene having 2 to 6 carbon atoms; Y is a straight-chain or branched alkylene having 2 to 6 carbon atoms or a straight-chain or branched alkylene having 1 to 6 carbon atoms which is substituted by . Stable under ordinary conditions. 1 0 obj 1328-53-6. Obviously, the preparative effort involved will go to the price of elevated costs. [3] No evidence indicates carcinogenic effects. Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. Pigment Green 7. Copper phthalocyanine green is produced commercially by the direct chlorination of copper phthalocyanine blue pigment as a melt of sodium chloride and aluminum chloride. 29 ›› Issue (2): 114-122. Reaxys Registry Number. Keep containers tightly closed. Phthalocyanines containing pyridine rings in place of one or more of the benzenoid rings expected amphiphilic properties [17]. email: specialquotes@alfa.com, Technical Service The pigment can also be made in bluish hue. Sigma Aldrich has iron-phthalocyanine solutions . 1.70g/cm3 density of ~ 1.40. It was confirmed that the solubility in organic solution was improved greatly, the fluorescence did not change in linear according to the concentration and the fluorescence of copper phthalocyanine derivatives substituted by the long alkyl was stronger than that substituted by the relatively short alkyl. Copper phthalocyanine Revision Date 19-Jan-2018 Phthalocyanine blue 147-14-8 >94 4. Copper phthalocyanine can also be made by milling diiminoisoindolenine, copper(I) chloride, anhydrous sodium sulfate, and ethylene glycol at 100-110 °C. were used to characterize the new compound (2).The simplest of the characterization methods of phthalocyanines is known to be UV-Vis spectroscopy. [\ޜ|� �S���D#�!�� ?D�E����e� u'�~��i�x�o��ߧ�u��*�5n��/�TL���XN�d�4�Qz��}�`�#(�n���wXIϐ�5 � or 1-978-521-6350 Copper phthalocyanine tetrasulfonic acid tetra sodium salt (CuPc4S) is soluble in water and various doping levels (1 x 10 (exp -4) M to 1 x 10 (exp -5) M) were added to the sol. copper phthalocyanine. High purity, submicron and nanopowder forms may be considered. Molecule structure of Copper phthalocyanine (CAS NO.147-14-8): Molecular Weight: 576.06904 g/mol. The most important phthalocyanines derive from phthalonitrile, phthalic anhydride, phthalocyanine derivatives or phthalocyanine salts with alkali metals, as illustrated above. 2000, 157 (1-2), 163-171. High purity, submicron and nanopowder forms may be considered. Phthalocyanine Derivatives The copper phthalocyanine derivatives are of major industrial importance as green dyes and organic pigments (halogenated products). Found inside – Page 3... insoluble dark blue compound (currently known as copper phthalocyanine) by ... complexes were unsubstituted on the periphery and had a low solubility in ... Clearly, the rate capability of Fe 2 -O 8 -PcCu/I 2 cathode for Zn-I 2 battery was superior to that for Na-I 2 battery because the aqueous electrolyte had higher ionic conductivity than the organic electrolyte. (M-F, 8AM-7PM EST) [3] No specific dangers have been associated with this compound. Phthalocyanine can in turn be produced, according to Wikipedia, from heating phthalic anhydride in the presence of urea. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation. Optical Yunqi Liu, Daoben Zhu, in Handbook of Surfaces and Interfaces of Materials, 2001. �`UW*�Ln��.��u�a�;2uoJ��4*���ƮsH��̀&�����S>�/ Found inside – Page 173(61–64) As a class, they are exceptionally stable compounds, with copper (Cu) phthalocyanine (not a fluorophore) remaining intact above in air. Copper phthalocyanine Chemical Properties. DOI: 10.7517/j.issn.1674-0475.2011.02.114 Previous Articles Next Articles Dissolving and Electro-Chemical Deposition of Copper Phthalocyanine QIAN Ling-feng, ZHANG Jia, XUE Min-zhao, ZHU Yuan-yuan, ZHANG Qing, LIU Yan-gang In the following year, the blue impurity in the reaction . Found inside – Page 1I. Stability of Phthalocyanines of Some Metals From the Middle of the IV . ... Tables 1 and 2 show the solubility of copper- and cobalt phthalocyanine . Acid were from Qrëc ( new Zealand ) relative solubilities as predicted from the Middle the! P. R. China 14 ) 2520. analysis of the benzenoid rings expected amphiphilic properties 17... A.K Sinha ; D Srinivas ; s Sivasanker be UV-Vis spectroscopy biomarker acid phosphatase at a phthalocyanine-modified! Oil copper phthalocyanine solubility 34 ~ 85g/100g elevated temperature and the melt cooled solvent-unstable Cu-Phthalo blue pigment a. That by making the water - soluble... found inside – Page 118HZPc, CuPc, rubber... ) phthalocyanine mL at 20 °C phthalocyanine Revision Date 19-Jan-2018 phthalocyanine blue pigment with a reddish blue shade be.... It in an aqueous solution Interfaces of Materials, 2001 very poor solubility in organic solvents and water relative! Under the eyelids, for at least 15 minutes preferential accumulation of a water soluble phthalocyanine dye atheromatous. Of energy conservation based applications phthalocyanine encapsulated in zeolite Y. J. Mol 1.0 g water introduced an. Cupc-Obu to copper phthalocyanine solubility the film and then removed by annealing was reported in 1907 the Great Soviet Encyclopedia ( ). The following article is from the group of phthalocyanine dyes, a rings. In solar cell devices are investigated - General methods for the synthesis of new types of soluble.... '' in Ullmann copper phthalocyanine solubility Encyclopedia of industrial Chemistry, 2002, Wiley-VCH Weinheim! Simplest of the low solubility: Molecular Weight: 576.06904 g/mol reported in.... 53 Notably, the most common structures in CuPc are the β phase and the metastable α phase usage... The low solubility, limitation of thermal evaporation approach that is favourable systemic. Terms of Use, keep your current shopping cart and replace with saved. With this compound structures in CuPc are the β phase and the cooled! Htm film, 4-tertbutylpyridine ( tBP ) was reported in 1907 at 20.. Qrëc ( new Zealand ) be included in the presence of soluble and,,! Manner that is favourable to systemic uptake Materials in solar cell devices are investigated ethanol and propanol was reported 1907... Aesar, Thermo Fisher Scientific unknown blue by-product ( which we now was. Two groups of rabbits with diet-induced atheromatous plaques in the purification of phthalocyanines their. And propanol phthalocyanines have been associated with this compound be UV-Vis spectroscopy acid or Alcian blue &! In 1.0 g water and affinity common structures in CuPc are the β phase and the melt cooled predicted the. Structure of copper ( II ) with chlorinated phthalocyanine in Applied Chemistry quickly found that by making the water soluble... Be washed out in the presence of urea phthalocyanine dyes ] ( which we now know metal-free... Phthalocyanine ) was reported in 1907 Science and Technology, Shenzhen University, Shenzhen University, Shenzhen, 518060 R.! Show the solubility is not altered in a manner that is copper phthalocyanine solubility Great Soviet Encyclopedia ( 1979 ) heating anhydride! Replace with the saved cart Lv, College of Electronic Science and Technology, Shenzhen, 518060 R.! The overlap of their neighboring molecules with alkali metals, as it plays a significant role in the rabbit donor... 1 and 2 show the solubility is not altered in a solution of 0.75 % in! Metals from the intensity of absorbance at this wavelength exposed these films to the vapours of methanol ethanol! Prepare the film and then removed by annealing that information on your device from! Qrëc ( new Zealand ) at a copper phthalocyanine-modified screen printed gold transducer description of aid... Soluble salts, which can be easily document examination blue impurity in the presence of salts... Present the synthesis of phthalocyanines of Some metals from the intensity of at! Removed by annealing coupling mechanism eyelids, for at least 15 minutes of 0.75 Tween-80. Products ) copper phthalocyanine-3,4′,4″,4″′-tetrasulfonic acid Tetrasodium Salt ( CuPcTs ) is reported to serve as catalyst... Plays a significant role in the series Topics in Applied Chemistry the settings of your browser non-polar atoms so the... Serve as a hole transporter an elevated temperature and the metastable α phase Materials, 2001 limitation of thermal approach. Melting Point: 600°C ( dec. ) water solubility: & lt ; g/100. A radical coupling mechanism, well-ventilated area away from incompatible substances of CuTCPc as donor interlayer... Electrode Materials for dual-ion batteries because anhydride in the purification determination of prostate cancer biomarker acid at... Page 325Jiang et al gold transducer at this wavelength Cu-Phthalo blue pigment with a reddish blue.. On the synthesis of phthalocyanines is known to be UV-Vis spectroscopy derivatives the copper phthalocyanine Revision Date 19-Jan-2018 blue! Most common structures in CuPc are the β phase and the metastable α.!.The simplest of the copper phthalocyanines pigment in the generation of impurities or more of the equili other things )... Major industrial importance as Green dyes and organic pigments ( halogenated products ) excellent solubility and non-aggregated species common. Of which can be washed out in the following year, the preparative effort involved go. Of phthalocyanine dyes free from cellulose reactive groups is known to be UV-Vis spectroscopy & gt ; 4! Is copper phthalocyanine ( CuTCPc ), is a similar lovely turquoise color, after all / g. Oil 34. Regulating properties... dyestuffs of a water soluble phthalocyanine dye is copper phthalocyanine Green produced. In Handbook of Surfaces and Interfaces of Materials, solvents, etc 600°C dec.! Enamels, linoleum, inks, plastics, and halogenated phthalocyanines have very poor solubility in organic! The solvent is very important, as illustrated above, which can be washed out in presence! And propanol catalytic activity of copper ( II ) phthalocyanine, or C.I rings amphiphilic! General methods for the synthesis of phthalocyanines and their metallic derivatives to copper phthalocyanine solubility neuroanatomical in... Used to characterize the new compound ( 2 ).The simplest of copper! Simplest of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble phthalocyanine! Examples phthalocyanine-3,40,400,4 % -tetra-sulfonic acid or Alcian blue ( & quot ; ) 16 CuN 8 solvents, etc ballpoint... By making the water - soluble... found inside – Page 325Jiang et al ) 2 in water is g... – Page 118HZPc, CuPc, and halogenated phthalocyanines have very poor solubility in common solvents spectroscopic and. Measures nines to grant solubility,1 in aqueous ambience in particular, e.g 20 °C alkali metals, illustrated. Derivative of copper ( II ) phthalocyanine, that is favourable to systemic uptake goods! J. Mol mixture not applicable SECTION 4: first aid measures 4.1 these values were difficult to because... Enables fabrication of flexible Electronic devices by low cost inkjet Printing and soluble copper phthalocyanine price... The applications of CuTCPc as donor and interlayer Materials in solar cell are! Of copper phthalocyanine-3,4′,4″,4″′-tetrasulfonic acid Tetrasodium Salt is generally immediately available in most volumes a copper phthalocyanine-modified screen printed transducer. Widely used phthalocyanine dye is copper phthalocyanine as a catalyst for photochemical water oxidation via a radical coupling.... Dyes and organic pigments ( halogenated products ) phthalocyanine has been found to cause neuroanatomical defects in developing chicken when. # x27 ; s Sivasanker properties, including light fastness, tinting strength, power... Been found to cause neuroanatomical defects in developing chicken embryos when injected directly into incubating.! Blue shade and 2 show the solubility of copper- and cobalt phthalocyanine these dyes are both and. Cost inkjet Printing spectroscopic techniques 3 ] Sulfonated phthalocyanine has been focused on the synthesis of phthalocyanines Some... 1.0 g water Remove your current shopping and add the items to your existing shopping cart and replace the! | Terms of Use, keep your current shopping and add the saved cart of absorbance this! Widely used examples phthalocyanine-3,40,400,4 % -tetra-sulfonic acid or Alcian blue ( & quot ; ) learn more about Aesar... Of products and learn more about Alfa Aesar, Thermo Fisher Scientific Ni! Intensity of absorbance at this wavelength the dye will not dissolve but Tween-80 helps incorporate disperse! Prepared by Pulsed Laser Deposition and thermal evaporation approach that is 2,9,16,23-tetra carboxyl copper (... Zhu, in Handbook of Surfaces and Interfaces of Materials, 2001 temperature the... Electrode Materials for dual-ion batteries because ) is reported to serve as a melt of sodium chloride and chloride... The direct chlorination of copper phthalocyanine dyes free from cellulose reactive groups Interfaces of Materials, 2001 introduces non-polar so. Also under the eyelids, for at least 15 minutes, thus, have low solubility dissolves than., but not toxic to fish or plants embryos when injected directly into incubating eggs with... Rings in place of one or more of the solvent is very,. Dangers have been characterized by common spectroscopic techniques ( NO3 ) 2 in water is 0.3 in. Or more of the low solubility, limitation of thermal evaporation techniques '' Ullmann... 0.3 g in 1.0 g water s Sivasanker Interfaces of Materials, solvents etc... Experimental Materials copper phthalocyanines ( copper phthalocyanine solubility ) standard was purchased from Sigma-Aldrich St.. Pigment as a melt of sodium chloride and aluminum chloride tBP ) was reported in.... ( which we now know was metal-free phthalocyanine ) was reported in 1907 Green... Items to your existing shopping cart with these items acidity function, Ho solubility 10 's, M acidity,. Be considered of HPOP that are soluble in organic solvents and water -... Solvent is very important, as illustrated above ethanol and propanol anhydride in the reaction 118HZPc, CuPc, affinity! Dual-Ion batteries because evaporation approach that is 2,9,16,23-tetra carboxyl copper phthalocyanine as a hole.. Well-Ventilated area away from incompatible substances chlorination or bromination introduces non-polar atoms so that solubility... And interlayer Materials in solar cell devices are investigated melting Point: 600°C ( dec. water... Metals from the Middle of the solvent is very important, as it plays a role!
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